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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 6(69), p. m326-m327, 2013

DOI: 10.1107/s1600536813012695

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catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ3O1,N:O2;κ3O2:N,O1}] iodide]

Journal article published in 2013 by Svitlana R. Petrusenko, Oleg M. Stetsyuk, Irina V. Omelchenko ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title one-dimensional coordination polymer, {[Mn(C10H12NO3)2]I} n , the potentially tetra-dentate (O,O,O,N) 2-[(2-hy-droxy-eth-yl)imino-meth-yl]-6-meth-oxy-phenol (H2 L) ligands are mono-deprotonated (as HL (-)) and coordinated by the metal ions in a tridentate chelate-bridging fashion [2.0111112]. The Mn(III) atom possesses a distorted trans-MnO4N2 octa-hedral coordination environment. The bridging ligands lead to [010]-chain polymeric cations {[Mn(HL)2](+)} n in the crystal. The charge-balancing iodide ions are disordered over two sites in a 0.690 (2):0.310 (2) ratio and a weak O-H⋯I hydrogen bond occurs. The crystal studied was found to be a racemic twin.