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ECS Meeting Abstracts, 21(MA2008-02), p. 1756-1756, 2008

DOI: 10.1149/ma2008-02/21/1756

The Electrochemical Society, ECS Transactions, 44(16), p. 125-135, 2009

DOI: 10.1149/1.3224749

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Oxidation of Carbon/Carbon through Coating Cracks

Journal article published in 2009 by Nathan Jacobson ORCID, Don Roth, Richard Rauser, James Cawley, Donald Curry
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Reinforced carbon/carbon (RCC) is used to protect the wing leading edge and nose cap of the Space Shuttle Orbiter on re-entry. It is composed of a lay-up of carbon/carbon fabric protected by a SiC conversion coating. Due to the thermal expansion mismatch of the carbon/carbon and the SiC, the SiC cracks on cool-down from the processing temperature. The cracks act as pathways for oxidation of the carbon/carbon. A model for the diffusion controlled oxidation of carbon/carbon through machined slots and cracks is developed and compared to laboratory experiments. A symmetric cylindrical oxidation cavity develops under the slots, confirming diffusion control. Comparison of cross sectional dimensions as a function of oxidation time shows good agreement with the model. A second set of oxidation experiments was done with samples with only the natural craze cracks, using weight loss as an index of oxidation. The agreement of these rates with the model is quite reasonable.