Published in

Elsevier, Journal of Natural Gas Science and Engineering, (25), p. 134-139

DOI: 10.1016/j.jngse.2015.04.035

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Thermodynamics phase changes of nanopore fluids

Journal article published in 2015 by Akand W. Islam ORCID, Tad W. Patzek, Alexander Y. Sun ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The van der Waals (vdW) equation (Eq.) is modified to describe thermodynamic of phase behavior of fluids confined in nanopore. Our aim is to compute pressures exerted by the fluid molecules and to investigate how they change due to pore proximity by assuming the pore wall is inert. No additional scaling of model parameters is imposed and original volume and energy parameters are used in the calculations. Our results clearly show the phase changes due to confinement. The critical shifts of temperatures and pressures are in good agreement compared to the laboratory data and molecular simulation. Peng-Robinson (PR) equation-of-state (EOS) has resulted in different effect than the vdW. This work delivers insights into the nature of fluid behavior in extremely low-permeability nanoporous media, especially in the tight shale reservoirs, below the critical temperatures.