Royal Society of Chemistry, RSC Advances, 25(5), p. 19301-19305, 2015
DOI: 10.1039/c4ra17015f
Wiley-VCH Verlag, ChemInform, 29(46), p. no-no, 2015
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The addition reactions between aromatic azoarenes and N-substituted formamides are described. This direct and practical method provides a novel approach for the synthesis of formylhydrazines and semicarbazides in the presence of NaI/DTBP and imidazole/DCP catalytic systems, respectively. It can be seen that C–H or C–N from N-substituted formamides could be cleaved selectively under such transition-metal-free conditions. This is the first successful example of direct addition of N-substituted formamides to N=N bond.