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Elsevier, Carbohydrate Research, 9(345), p. 1088-1093

DOI: 10.1016/j.carres.2010.03.024

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An unexpected rearrangement giving a new thiosubstituted carbohydrate

Journal article published in 2010 by Agathe Martinez, Eric Hénon, Claire Coiffier, Aline Banchet, Dominique Harakat, Jean-Marc Nuzillard ORCID, Arnaud Haudrechy
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A new thiosubstituted 'd-arabino'-type derivative was obtained from an open carbohydrate via a cascade of four consecutive transformations in a single reaction process. Molecular orbital computations were also performed to explain the stereochemical outcome of the reaction.