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Elsevier, Mendeleev Communications, 6(21), p. 320-322

DOI: 10.1016/j.mencom.2011.11.009

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Reactivity of extended chalcogen-nitrogen π-systems: Compounds Ar-Se-N=S=N-Se-Ar

This paper is available in a repository.
This paper is available in a repository.

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Abstract

The reactions of Ar–Se–N=S=N–Se–Ar with SO2Cl2 (as well as with ArSeCl and p-TolICl2) and H2O gave Ar–SeCl2–N=S=N–Se–Ar and [NH4]+[ArSeSO3]– (Se-Bunte salts), respectively, whose structures were confirmed by X-ray diffraction.