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A 3D hierarchical meso- and macroporous Na3 V2 (PO4 )3 -based hybrid cathode with connected Na ion/electron pathways is developed for ultrafast charge and discharge sodium-ion batteries. It delivers an excellent rate capability (e.g., 86 mA h g(-1) at 100 C) and outstanding cycling stability (e.g., 64% retention after 10 000 cycles at 100 C), indicating its superiority in practical applications.