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Elsevier, Journal of Nuclear Materials, (465), p. 653-656, 2015

DOI: 10.1016/j.jnucmat.2015.06.055

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Heat capacity of Bi 2 UO 6

Journal article published in 2015 by Karin Popa ORCID, Ondrej Beneš, Philippe E. Raison, Jean-Christophe Griveau, Philipp Pöml, Eric Colineau, Rudy J. M. Konings, Joseph Somers
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the frame of the safety of lead-bismuth eutectic cooled fast reactors, the thermal behaviour of bismuth(III) uranate(VI) was studied as a possible interaction product of the coolant and mixed oxide fuel. The heat capacity of Bi2UO6 were measured and presented here for the first time. The thermodynamic functions derived at T = 298.15 K are Cp(298.15 K) = 185.1 J K-1 mol-1, S°(298.15 K) = 238.8 J K-1 mol-1, and {H°(298.15 K)-H°(0 K)} = 34863 J mol-1.