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American Physical Society, Physical review E: Statistical, nonlinear, and soft matter physics, 2(75), 2007

DOI: 10.1103/physreve.75.021501

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Confinement-induced liquid ordering investigated by x-ray phase retrieval

This paper is available in a repository.
This paper is available in a repository.

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Data provided by SHERPA/RoMEO

Abstract

Using synchrotron x-ray diffraction, we have determined the ensemble-averaged density profile of colloidal fluids within confining channels of different widths. We observe an oscillatory ordering-disordering behavior of the colloidal particles as a function of the channel width, while the colloidal solution remains in the liquid state. This phenomenon has been suggested by surface force studies of hard-sphere fluids and also theoretically predicted, but here we see it by direct measurements of the structure for comparable systems.