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Optica, Optics Express, 9(18), p. 9628, 2010

DOI: 10.1364/oe.18.009628

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Nonlinear spectra of ZnO: Reverse saturable, two- and three-photon absorption

Journal article published in 2010 by M. G. Vivas ORCID, T. Shih, T. Voss, E. Mazur, C. R. Mendonca
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

We present a broadband (460 - 980 nm) analysis of the nonlinear absorption processes in bulk ZnO, a large-bandgap material with potential blue-to-UV photonic device applications. Using an optical parametric amplifier we generated tunable 1-kHz repetition rate laser pulses and employed the Z-scan technique to investigate the nonlinear absorption spectrum of ZnO. For excitation wavelengths below 500 nm, we observed reverse saturable absorption due to one-photon excitation of the sample, agreeing with rate-equation modeling. Two- and three-photon absorption were observed from 540 to 980 nm. We also determined the spectral regions exhibiting mixture of nonlinear absorption mechanisms, which were confirmed by photoluminescence measurements.