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Wiley, Angewandte Chemie International Edition, 26(43), p. 3471-3473
Wiley, Angewandte Chemie, 26(116), p. 3553-3555, 2004
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A Staudinger Approach towards Binol-Derived MAP-Type Bidentate P,N Ligands
Journal article published in 2004 by
Peter N. M. Botman,
Olivier David,
Alessia Amore 
,
Jasper Dinkelaar,
Martin T. Vlaar,
Kees Goubitz,
Jan Fraanje,
Henk Schenk,
Henk Hiemstra,
Jan H. van Maarseveen
,
Jasper Dinkelaar,
Martin T. Vlaar,
Kees Goubitz,
Jan Fraanje,
Henk Schenk,
Henk Hiemstra,
Jan H. van Maarseveen
This paper is available in a repository.
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Abstract
The axially chiral BICOL backbone was functionalised with two third generation carbosilane dendritic wedges and further elaborated to a phosphoramidite ligand. High enantioselectivities were obtained when these monodentate ligands were applied in the rhodium-catalysed asymmetric hydrogenation of methyl 2-acetamidocinnamate.