Published in

Wiley-VCH Verlag, ChemInform, 1(33), p. no-no, 2010

DOI: 10.1002/chin.200201218

Elsevier, Tetrahedron Letters, 40(42), p. 7003-7005

DOI: 10.1016/s0040-4039(01)01456-3

Links

Tools

Export citation

Search in Google Scholar

A short synthesis of (1S,8aR)-1-aminomethyl indolizidine. The heterocyclic core of stelletamides

Journal article published in 2001 by Ronaldo A. Pilli ORCID, Paulo R. Zanotto, Maria Alice Böckelmann
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Red circle
Preprint: archiving forbidden
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

(1S,8aR)-1-Aminomethyl indolizidine (2), the heterocylic core of the stelletamide alkaloids, was prepared in five steps and ca. 20% overall yield starting from oxazolidin-2-one 7. The key step involved the stereoselective addition of the preformed titanium (IV) enolate from 7 to the N-acyliminium ion derived from 2-methoxy piperidine 8b.