Wiley-VCH Verlag, ChemInform, 1(33), p. no-no, 2010
Elsevier, Tetrahedron Letters, 40(42), p. 7003-7005
DOI: 10.1016/s0040-4039(01)01456-3
Full text: Unavailable
(1S,8aR)-1-Aminomethyl indolizidine (2), the heterocylic core of the stelletamide alkaloids, was prepared in five steps and ca. 20% overall yield starting from oxazolidin-2-one 7. The key step involved the stereoselective addition of the preformed titanium (IV) enolate from 7 to the N-acyliminium ion derived from 2-methoxy piperidine 8b.