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American Physical Society, Physical review B, 11(70), 2004

DOI: 10.1103/physrevb.70.115106

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Nonlinear optical scattering: The concept of effective susceptibility

Journal article published in 2004 by Sylvie Roke, Mischa Bonn, Andrei V. Petukhov ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We present a general theoretical method for deriving effective susceptibilities for (non)linear optical scattering processes of arbitrary order using the reciprocity principle. This method allows us to formulate a generalized treatment of nonlinear optical scattering and deduce selection rules independent of the precise mechanism of light-matter interaction. We particularize this approach to second-order sum frequency scattering from an inhomogeneous medium and consider the limiting cases of small particle scattering, refractive index matched (Rayleigh-Gans-Debye) scattering, small refractive index contrast (Wentzel-Kramers-Brillouin) scattering and correlated scattering. We compare the derived expressions to experimental results of sum frequency scattering from monodisperse particles in suspension with varying sizes.