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American Chemical Society, Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 14(101), p. 2546-2551, 1997

DOI: 10.1021/jp9630885

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Time-Dependent Stokes Shift and Its Calculation from Solvent Dielectric Dispersion Data

Journal article published in 1997 by Chao-Ping Hsu ORCID, Xueyu Song, R. A. Marcus, Marcus Ra
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The time-dependent solvation correlation function (the Stokes shift response function), which describes the solvent response to a sudden change in the charge distribution of a solute molecule, is calculated here directly from experimentally measured dielectric dispersion data, ε(ω), of the solvent. In the calculation a reaction field with the dielectric continuum assumption is used. This simple model is applied to the experimental results of Jimenez et al. for photoexcited coumarin and water as a solvent, and encouraging agreement is obtained using the experimental data on ε(ω).