European Geosciences Union, Atmospheric Chemistry and Physics, 2(11), p. 529-542, 2011
Full text: Download
Abstract. We report measurements of bromoform made by gas chromatography during the OP3 campaign in 2008. Measurements were made simultaneously for a few days at the World Meteorological Organization (WMO) Global Atmospheric Watch (GAW) site in the Danum Valley, a rainforest location in Sabah, Borneo, and at a nearby coastal site at Kunak. Background values at Kunak were higher than those measured in the rainforest (2–5 ppt compared with 1 ppt) and excursions away from the background were very much higher, reaching 10 s of ppt. Measurements of C2Cl4, an industrial tracer, showed no significant difference in background at the two sites. Modelling using two different models can reproduce a number of the observed features. The data are consistent with a strong, local coastal source of bromoform in eastern Sabah and can be used to infer the strength of the source of bromoform in South East Asia. However, they provide only a very weak constraint on global emissions. The global model results highlight the difficulty for short-lived species of extrapolating limited duration, local measurements to a global source.