We report new experimental results on enhanced second harmonic generation using a structural light focusing phenomenon in photonic crystals (PCs). We use opal-based PC, infiltrated with NaNO2 and pumped with femtosecond laser pulses at various incidence angles, in order to examine the dependence of second harmonic generation efficiency on the pumping wavelength location toward the PC band-gap. We demonstrate one order enhancement of second harmonic generation in case of PC band-gap pumping in comparison to non-band-gap pumping. Second harmonic generation is performed in reflection mode with the maximum of generation in the direction of mirror reflection. We demonstrate that the spectrum of second harmonic does not narrow with the quasi-phase matching condition in case of band-gap generation, and second harmonic spectrum corresponding to non-band-gap generation undergoes 1.5 times narrowing due to the quasi-phase matching.