We investigated the effect of different stacking sequences of carbon and basalt fabrics on the flexural properties of hybrid composite laminates. The hybrid composites were fabricated using a vacuum-assisted resin transfer molding process. Three-point bending test was performed and the fracture surfaces were examined by scanning electron microscopy. The present results showed that the flexural strength and modulus of hybrid composite laminates were strongly dependent on the sequence of fiber reinforcement. All the stacking sequences showed a positive hybridization effect. The interply hybrid composite with carbon fiber at the compressive side exhibited higher flexural strength and modulus than when basalt fabric was placed at the compressive side. Here, the proper stacking sequence of basalt and carbon fiber layers was found to improve the balance of the mechanical properties of the hybrid composite laminate.