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Wiley, ChemPhysChem, 1(10), p. 199-205, 2009

DOI: 10.1002/cphc.200800350

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How Fast is a Fast Equilibrium? A New View of Reversible Reactions

Journal article published in 2009 by Carlos Baleizão ORCID, Mário N. Berberan Santos ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Reversible reactions are described in terms of kinetic cycles. From this description, two useful parameters arise: 1) average cycle duration and 2) average number of cycles. The latter applies to cycles with at least one unstable species. These parameters allow answering the question "How fast is a fast equilibrium?" in absolute and in relative terms, respectively. The general interest of the approach is demonstrated by application to reactions drawn from several areas: Acid-base equilibria, enzyme kinetics, excited-state proton transfer, thermally activated delayed fluorescence, monomer-excimer kinetics and homo-FRET.