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Elsevier, Atmospheric Environment, 28(38), p. 4769-4778

DOI: 10.1016/j.atmosenv.2004.04.036

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Significant growth in surface ozone at Mace Head, Ireland, 1987–2003

Journal article published in 2004 by P. G. Simmonds, R. G. Derwent ORCID, A. L. Manning, G. Spain
This paper is available in a repository.
This paper is available in a repository.

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Data provided by SHERPA/RoMEO

Abstract

Background ozone O3 observations at Mace Head on the west coast of Ireland since 1987 show a significant positive trend of 0.49±0.19 ppb year−1 through to 2003. Increasing trends are observed for all seasons, with the largest trends during the winter season, 0.63±0.31 ppb year−1 and the smallest trends during the summer, 0.39±0.25 ppb year–1. However, this growth rate has not been consistent over time with a major anomaly evident in 1998–1999. This major O3 perturbation is correlated with variations of CO2, CO, CH4, H2 and CH3Cl, which are likely due to large-scale biomass burning events in tropical and boreal regions during 1997–1999 coupled with an intense El Niño event. Over the 16 years of observations background O3 has increased by about 8 ppb (∼24%) in the clean oceanic sectors representative of the Northern Hemisphere marine boundary layer.