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American Chemical Society, Crystal Growth and Design, 1(10), p. 7-10, 2009

DOI: 10.1021/cg900748r

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Different Structural Networks Determined by Variation of the Ligand Skeleton in Copper(II) Diphosphinate Coordination Polymers

Journal article published in 2010 by Ferdinando Costantino, Andrea Ienco ORCID, Stefano Midollini
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A new polymeric copper(II)-organic framework. [[Cu(4,4'-bipy)(p(xyl)p)(H2O)(2)]center dot 2(H2O)](n) (1; p(xyl)p = P,P'-diphenyl-p-xylenediphosphinate, 4,4'-bipy = 4,4'-bipyridine), has been synthesized. Single-crystal X-ray diffraction revealed that the structure of I consists of 2D grids connected by solvent water molecules, The temperature-dependent X-ray powder diffraction analysis of I has shown file formation of a dehydrated phase well modeled by a 3D structure with it binodal 4,6 connected topology.