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Wiley, Journal of Polymer Science Part A: Polymer Chemistry, 3(46), p. 947-957, 2007

DOI: 10.1002/pola.22438

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Synthesis and characterization of ethylene‐propylene‐1‐pentene terpolymers

Journal article published in 2007 by Marco Antônio da Silva, Griselda Barrera Galland ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Ethylene (E), propylene (P), and 1-pentene (A) terpolymers differing in monomer composition ratio were produced, using the metallocenes rac-ethylene bis(indenyl) zirconium dichloride/methylaluminoxane (rac-Et(Ind)2ZrCl2/MAO), isopropyl bis(cyclopentadienyl)fluorenyl zirconium dichloride/methylaluminoxane (Me2C(Cp)(Flu)ZrCl2/MAO, and bis(cyclopentadienyl)zirconium dichloride, supported on silica impregnated with MAO (Cp2ZrCl2/MAO/SiO2/MAO) as catalytic systems. The catalytic activities at 25 °C and normal pressure were compared. The best result was obtained with the first catalyst. A detailed study of 13C NMR chemical shifts, triad sequences distributions, monomer-average sequence lengths, and reactivity ratios for the terpolymers is presented. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 947–957, 2008