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Elsevier, Journal of Chemical Thermodynamics, 7(42), p. 886-890

DOI: 10.1016/j.jct.2010.02.014

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Ternary mutual diffusion of isoniazid in aqueous sodium chloride, sodium hydroxide, and hydrochloric acid at T=298.15K

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Abstract

Ternary mutual diffusion coefficients measured by Taylor dispersion method (D11, D22, D12, and D21) are reported for aqueous solutions containing isoniazid and different electrolytes (NaCl, NaOH, or HCl) at T = 298.15 K at different carrier concentrations. These diffusion coefficients have been measured having in mind a better understanding of the structure of these systems and the thermodynamic behaviour of isoniazid in different media. For example, it is possible to make conclusions about the influence of these electrolytes in diffusion of isoniazid, and to obtain information concerning the number of moles of each component transported per mole of the other component driven by its own concentration gradient.