American Chemical Society, Journal of the American Chemical Society, 36(128), p. 11734-11735, 2006
DOI: 10.1021/ja063538z
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A metal-organic framework, PCN-9, containing entatic metal centers, has been synthesized and crystallographically characterized. The H2 and CH4 adsorption enthalpies of PCN-9 are among the highest reported thus far.