Published in
Elsevier, Inorganic Chemistry Communications, (31), p. 54-57
DOI: 10.1016/j.inoche.2013.02.019
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An unusual silver–ethynide polymeric chain containing centrosymmetric Ag14 cluster segments stabilized by mixed carboxylate ligands
Journal article published in 2013 by
Yun-Peng Xie,
Shaeel A. Al-Thabaiti 
,
Mohamed Mokhtar,
Thomas C. W. Mak
,
Mohamed Mokhtar,
Thomas C. W. Mak
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Abstract
Fromthe reaction of AgC=C'Bu with 9-hydroxy-9-fluorenecarboxylic acid (HL) and AgCF3CO2, we have isolated a newtype of organosilver(I) coordination polymeric chain, namely {[Ag14(C=C'Bu)8(L)2(CF3CO2)4].2CH3OH}n, which contains centrosymmetric [Ag14(C=C'Bu)8(CF3CO2)2]4+ cluster segments bridged by pairs of L and trifluoroacetate ligands.