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American Chemical Society, Journal of the American Chemical Society, 39(131), p. 13912-13913, 2009

DOI: 10.1021/ja905713t

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Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IVC−H Bond Functionalization Catalysis

Journal article published in 2009 by Polly L. Arnold ORCID, Melanie S. Sanford, Stephen M. Pearson
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

A Pd(IV) complex that represents a viable catalytic intermediate in Pd-catalyzed C-H bond halogenation reactions has been isolated and structurally characterized. It contains the first examples of both a Pd(IV) NHC bond and a Pd(IV) alkoxide bond and serves as a precatalyst for C-H bond halogenation. As such, this represents a new class of tunable supporting ligand systems in Pd(IV) catalysis.