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Wiley, Angewandte Chemie International Edition, 15(47), p. 2828-2831, 2008

DOI: 10.1002/anie.200705819

Wiley, Angewandte Chemie, 15(120), p. 2870-2873, 2008

DOI: 10.1002/ange.200705819

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[Mn6] under Pressure: A Combined Crystallographic and Magnetic Study

Journal article published in 2008 by Alessandro Prescimone, Constantinos J. Milios, Stephen Moggach, John E. Warren, Alistair R. Lennie, Javier Sanchez-Benitez ORCID, Konstantin Kamenev, Roland Bircher, Mark Murrie ORCID, Simon Parsons, Euan K. Brechin ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Folding under pressure: High-pressure crystallography of an Mn6 single-molecule magnet reveals dramatic changes in the intramolecular geometry of the magnetic core. These structural changes effect the magnetic properties of the molecule: the magnitude of the ferromagnetic exchange between the metals is decreased, and under extreme pressure switches to antiferromagnetic. © 2008, Wiley-VCH Verlag Berlin