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Elsevier, Journal of Organometallic Chemistry, (798), p. 209-213, 2015

DOI: 10.1016/j.jorganchem.2015.05.009

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Synthesis and properties of a series of carboranyl-BODIPYs

Journal article published in 2015 by Jaime H. Gibbs, Haijun Wang, N. V. S. Dinesh K. Bhupathiraju, Frank R. Fronczek, Kevin M. Smith ORCID, M. Graça H. Vicente, M. Graça H. Vicente
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A series of four BODIPYs containing one or two ortho- or para-carborane clusters were synthesized using palladium(0)-catalyzed Suzuki cross-coupling or nucleophilic substitution reactions, at the 2,6- or the 8-positions of halogenated boron dipyrromethenes (BODIPYs). The spectroscopic, structural (including one X-ray) and in vitro BBB permeability of the BODIPYs using hCMEC/D3 brain endothelial cells were investigated.