Published in

Wiley, Angewandte Chemie International Edition, 9(48), p. 1673-1676, 2009

DOI: 10.1002/anie.200805415

Links

Tools

Export citation

Search in Google Scholar

Revisiting Prussian Blue Analogues with Solid-State MAS NMR Spectroscopy: Spin Density and Local Structure in [Cd3{Fe(CN)6}2]⋅15 H2O

Journal article published in 2009 by Alexandrine Flambard, Frank H Köhler, Rodrigue Lescouëzec ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

No legendary Prussian order! The distribution of vacancies in Prussian blue analogues is not random, and the spin density on the Cd(2+) ion varies depending on the number of paramagnetic ions in its surroundings. This conclusion follows from (113)Cd solid-state magic-angle spinning NMR studies of [Cd(3){Fe/Co(CN)(6)}(2)] x 15 H(2)O, where the presence of small but significant spin density on the observed (113)Cd nucleus leads to improved spectral resolution.