The increasing interest in biogas production has brought notable attention to lignocellu-losic wastes as a promising and yet unexploited feedstock. As these materials are usually highly recalcitrant the energetic efficiency of biogas production, however, is comparatively low. With the aim to overcome this drawback, a novel cascaded approach was investigated that combines anaerobic digestion with hydrothermal carbonization (HTC). The latter is used to convert the digestate into a carbon-rich product termed hydrochar. An energetic evaluation of this cascaded treatment shows that the energy recovery can be nearly doubled compared to single anaerobic digestion. Furthermore, systematic HTC experiments with both fresh and digested wheat straw and with reaction temperatures of 190 C, 210 C, 230 C, and 250 C revealed an effect of reaction temperature on carbon, nitrogen, and phosphorus concentration in the final hydrochar. Carbon, nitrogen and phosphorus are primarily retained in the hydrochar, which could favor its use as soil ameliorant instead of an energy carrier.