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American Chemical Society, Crystal Growth and Design, 3(13), p. 1277-1289, 2013

DOI: 10.1021/cg3017358

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Syntheses, Topological Structures, and Photoluminescences of Six New Zn(II) Coordination Polymers Based on Mixed Tripodal Imidazole Ligand and Varied Polycarboxylates

Journal article published in 2013 by Di Sun ORCID, Zhi-Hao Yan, Vladislav A. Blatov ORCID, Lei Wang, Dao-Feng Sun
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Solvothermal reactions of tripodal ligand 1,3,5-tris(1-imidazolyl)benzene (tib) and different polycarboxylates with zinc nitrate provided six new zinc(II) coordination polymers (CPs), namely, {[Zn8(tib)5(bdc)8(H2O)]·7DMF·18H2O}n (1), {[Zn3(tib)2(bpdc)3]·5H2O}n (2), {[Zn(tib)(pdac)]·1.5H2O}n (3), {[Zn6(tib)2(pdac)3]·DMA·2H2O}n (4), {[Zn2(tib)2(pma)]·4H2O}n (5), {[Zn2(tib)(Htib)(H2pma)(Hpma)]·2H2O}n (6) (H2bdc = 1,3-benzenedicarboxylic acid, H2bpdc = 4,4′-biphenyldicarboxylic acid, H2pdac = 1,2-phenylenediacetic acid, H4pma = pyromellitic acid, DMF = N,N′-dimenthylformamide, DMA = N,N′-dimethylacetamide).