Isobaric vapor–liquid equilibrium data have been determined at 101.33 kPa for the binary mixtures of benzene-tetraethylene glycol (TeEG), toluene-TeEG and o-xylene-TeEG. The vapor-phase fugacity coefficients were calculated from the virial equation. The thermodynamic consistency of the data has been tested via Herington analysis. The binary parameters for four activity coefficient models (van Laar, Wilson, NRTL and UNIQUAC) have been fitted with the experimental data. A comparison of model performances has been made by using the criterion of root mean square deviations in boiling point and vapor-phase composition.