The progress of organic electronics demands an increased participation of nanotechnology, and it has already been shown that the presence of metallic nanoparticles and/or nanostructured thin films can enhance the device performance. Nevertheless, to gain control over the device final performance, it is crucial to achieve a profound understanding of the nanostructure development and assembly. We investigate the growth kinetics of silver (Ag) on a tris(8-hydroxyquinolinato)aluminum (Alq3) thin film via sputter deposition. The increase of the average electron density of the Ag nanostructured film is observed to follow a sigmoidal shape development as a function of the deposited Ag thickness, as a consequence of dominant island-mediated growth. The nanoclustered film is percolated at around a thickness of 5.0 ± 0.1 nm. At this film thickness the effective film density is about 50%. Moreover, our simulation results indicate that the shape of the nanoclusters changes from truncated spheres to cylinders upon surpassing the percolation threshold.