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Wiley-VCH Verlag, ChemInform, 15(29), p. no-no, 2010

DOI: 10.1002/chin.199815010

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ChemInform Abstract: Antiferromagnetic Ordering in the Novel Dy3Ge4 and DyGe1.3 Compounds Studied by Neutron Diffraction and Magnetic Measurements

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This paper is available in a repository.

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Abstract

The magnetic ordering of the novel binary compounds Dy3Ge4 and DyGe1.3(1) has been studied by neutron diffraction and magnetic measurements. Dy3Ge4 with the Er3Ge4 structure type (space group Cmcm) displays a two step antiferromagnetic ordering below TN = 19 K. The two Dy sites (Dy1:8(f) and Dy2:4(c)) order independently with two distinct order parameters associated with the same wave vector q = (0, 1, 0). Both sublattices have a uniaxial antiferromagnetic moment arrangement but with mutually perpendicular orientations. Dy1 orders below TN with the moments along the a-axis, Dy2 orders only below Ti = 6 K along the c-axis. At 1.4 K the moment values of Dy1 and Dy2 are 7.31(8) μB and 5.6(3) μB, respectively. Their arrangement leads to a symmetry reduction described by the monoclinic magnetic space group Cp1121′/mi′(Sh1155). The two-dimensional canted antiferromagnetic structure is the result of a strong magnetocrystalline anisotropy and the presence of various types of magnetic interactions. The phase of DyGe1.3(1) composition with the AlB2 structure type (space group P6/mmm) was detected as an impurity in the studied sample. It orders antiferromagnetically below TN = 16 K with collinear moment arrangement associated with a 2c-cell enlargement (q = 0, 0, 1/2) described by the magnetic space group P2c112′/m′(Sh1156). At 1.4 K μDy = 7.2(2) μB and is confined to the (001) plane.