Taylor and Francis Group, Synthetic Communications, 14(31), p. 2089-2096
DOI: 10.1081/scc-100104457
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Polysubstituted 4-cyano-4-phenylsulfonylbutyric esters are prepared by the addition of bromoacetate to 1-cyano-1-phenylsulfonyl alkenes mediated by Zn/Cp2TiCl2(cat.) at room temperature in good to high yield.