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American Chemical Society, Crystal Growth and Design, 4(5), p. 1639-1642, 2005

DOI: 10.1021/cg049556e

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3D Supramolecular Array Assembled by Cross-like Arrangement of 1D Sandwich Mixed Molybdenum−Vanadium Polyoxometalate Bridged Coordination Polymer Chains:  Hydrothermal Synthesis and Crystal Structure of {[MoVI5MoV3VIV8O40(PO4)][Ni(en)2]}[Ni(en)2]2·4H2O

Journal article published in 2005 by Cai-Ming Liu ORCID, De-Qing Zhang, Dao-Ben Zhu
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A novel organic−inorganic hybrid material constructed from mixed molybdenum−vanadium polyoxoanion clusters and [Ni(en)2]2+ complex groups {[MoVI5MoV3VIV8O40(PO4)][Ni(en)2]}[Ni(en)2]2·4H2O (1) (en = ethylenediamine), has been prepared under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction. Complex 1 exhibits an interesting three-dimensional supramolecular array through cross-like arrangement of a one-dimensional coordination polymer anion chain {[MoVI5MoV3VIV8O40(PO4)][Ni(en)2]}4-, which is sandwiched by discrete cation complex fragments [Ni(en)2]2+. It is the first example of a three-dimensional organic/inorganic hybrid polyoxometalate formed by cross-like arrangement of a one-dimensional polyoxometalate bridged coordination polymer chain.