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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 12(62), p. m3269-m3271, 2006

DOI: 10.1107/s1600536806043960

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Tetrakis(N-ethyl-9-oxo-4-azonia-5-aza-9H-fluorene) tetra-μ3-iodo-hexa-μ2-iodo-dodecaiodohexabismuthate

Journal article published in 2006 by Meredith A. Tershansy, Andrea M. Goforth, Mark D. Smith, LeRoy Peterson Jr, Hans-Conrad zur Loye ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The new iodobismuthate compound (C13H11N 2O)4[Bi6I22] has been synthesized solvothermally by reacting BiI3, Zn(NO3) 2·6H2O and 4,5-diazafluoren-9-one in a water/ethanol solvent mixture. The asymmetric unit of the compound contains two independent [N-ethyl-4,5-dafo]+ cations and one-half of a centrosymmetric [Bi6I22]4- anion. The average terminal Bi - I, Bi - μ2-I and Bi - μ3-I bond lengths in the anion are 2.8923 (2), 3.1403 (2) and 3.3022 (2) Å, respectively. © 2006 International Union of Crystallography All rights reserved.