Published in

Wiley, Angewandte Chemie International Edition, 17(48), p. 3082-3086, 2009

DOI: 10.1002/anie.200805302

Wiley, Angewandte Chemie, 17(121), p. 3128-3132, 2009

DOI: 10.1002/ange.200805302

Links

Tools

Export citation

Search in Google Scholar

Crystal-Structure Determination of Powdered Paramagnetic Lanthanide Complexes by Proton NMR Spectroscopy

Journal article published in 2009 by Gwendal Kervern, Anthony D'Aléo, Loïc Toupet, Olivier Maury ORCID, Lyndon Emsley, Guido Pintacuda
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

Shifts for crystals: Solid-state NMR spectroscopy can be used for structure determination of microcrystalline paramagnetic solids at natural isotopic abundance. The protocol makes use of paramagnetic effects, measured on suitably recorded (1)H NMR spectra, to define the conformation of a molecule in the lattice and the intermolecular packing in the solid phase. The method is illustrated with a family of lanthanide compounds (see picture).