Published in
American Chemical Society, Inorganic Chemistry, 4(46), p. 1233-1236, 2007
DOI: 10.1021/ic0616434
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Rationally Designed Micropores within a Metal−Organic Framework for Selective Sorption of Gas Molecules
Journal article published in 2007 by
Banglin Chen,
Shengqian Ma 
,
Shengqian,
Fatima Zapata,
Frank R. Fronczek,
Emil B. Lobkovsky,
Hong-Cai Zhou
,
Shengqian,
Fatima Zapata,
Frank R. Fronczek,
Emil B. Lobkovsky,
Hong-Cai Zhou
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Abstract
A microporous metal-organic framework, MOF, Cu(FMA)(4,4'-Bpe)0.5 (3a, FMA = fumarate; 4,4'-Bpe = 4,4'-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.6 A, which are interconnected by pore windows of 2.0 x 3.2 A, 3a shows highly selective sorption behaviors of gas molecules.