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Royal Society of Chemistry, Chemical Science, 2(3), p. 443-446

DOI: 10.1039/c1sc00644d

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Photocatalytic oxidation of water by polymeric carbon nitride nanohybrids made of sustainable elements

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The search for earth-abundant semiconductors and co-catalysts for wateroxidation is an important step towards conversion of solar energy into fuel chemicals in a sustainable manner. Here, we report the integration of Co3O4nanoparticles within graphitic carbon nitride to construct a nanohybrid photocatalyst made of abundant elements for the photocatalytic generation of oxygen from water, achieving an apparent quantum efficiency of 1.1% at 420 nm for water splitting to oxygen. The present system shows great promise in polymer photocatalysis for applications in future energy cycles based on sustainable materials.