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Wiley, Angewandte Chemie International Edition, 6(45), p. 989-993, 2006

DOI: 10.1002/anie.200502638

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Vitamin B12: A Methyl Group without a Job?

Journal article published in 2006 by Philip Butler, Marc-Olivier Ebert, Andrzej Lyskowski, Karl Gruber ORCID, Christoph Kratky, Bernhard Kräutler
This paper is available in a repository.
This paper is available in a repository.

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Abstract

(Chemical Equation Presented) At a record distance: The methyl group at C176 of the nucleotide loop of vitamin B12 derivatives has a significant effect on their characteristic "base-on"/"base- off" switch (see scheme), the constitutional result of which is a remarkable 11 bonds away from C176.