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International Union of Crystallography, Acta Crystallographica Section C: Crystal Structure Communications, 7(55), p. 1087-1090, 1999

DOI: 10.1107/s0108270199003881

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Diaquabis(2,2'-bipyridine-N,N')nickel(II) diperchlorate

Journal article published in 1999 by Y. Rodríguez-Martín, J. González-Platas ORCID, C. Ruiz-Pérez
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The structure of the title compound, [Ni(C10H8N2)2-(H2O) 2](ClO4)2, consists of monomeric [Ni(bipy)2-(H2O)2]2+ cations (bipy is 2,2′-bipyridine) and perchlorate anions. The Ni atom has octahedral coordination comprised of two water O atoms and four N atoms from two chelating bipy groups [mean values: Ni -Owater 2.089(5) and Ni - Nbipy 2.066 (6) Å]. Hydrogen bonding plays an important role in consolidating the crystal structure.