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Georg Thieme Verlag, Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, 01(24), p. 53-56

DOI: 10.1055/s-0032-1317760

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On the Oxidation of Different Iminic Bonds by Excess of 3-Chloroperbenzoic Acid

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the present work the behavior of different substituted iminic bonds toward the oxidative action of 3-chloroperbenzoic acid is reported. The C=N bond was or was not oxidized to oxaziridines, amides, oximes, nitroso-, nitro-, and azodioxy compounds depending on the substituents at the iminic group and on the ­imine/MCPBA stoichiometric ratio.