Published in
Elsevier, Journal of Organometallic Chemistry, 2(603), p. 235-239
DOI: 10.1016/s0022-328x(00)00190-x
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Synthesis and resolution of a new P-chiral hydroxy phosphine
Journal article published in 2000 by
Joan Albert,
J. Magali Cadena,
J. Magali Cadena,
Sergio Delgado,
Jaume Granell 
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Abstract
The synthesis of the functionalized P-chiral phosphine BzPhP{CH(OH)Ph}and its resolution by palladium metallacycles is reported. The cyclopalladated compound containing the primary amine 1-(1-naphthyl)ethylamine has been shown to be a better resolving agent for this phosphine than the corresponding metallacycle containing the tertiary amine N,N-dimethyl-1-(1-naphthyl)ethylamine