Elsevier, Journal of Organometallic Chemistry, 2(603), p. 235-239
DOI: 10.1016/s0022-328x(00)00190-x
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The synthesis of the functionalized P-chiral phosphine BzPhP{CH(OH)Ph}and its resolution by palladium metallacycles is reported. The cyclopalladated compound containing the primary amine 1-(1-naphthyl)ethylamine has been shown to be a better resolving agent for this phosphine than the corresponding metallacycle containing the tertiary amine N,N-dimethyl-1-(1-naphthyl)ethylamine