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Wiley, Angewandte Chemie International Edition, 45(46), p. 8593-8596, 2007

DOI: 10.1002/anie.200702534

Wiley, Angewandte Chemie, 45(119), p. 8747-8750, 2007

DOI: 10.1002/ange.200702534

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High-Activity, Single-Site Mesoporous Pd/Al2O3Catalysts for Selective Aerobic Oxidation of Allylic Alcohols

Journal article published in 2007 by Simon F. J. Hackett, Rik M. Brydson, Mhairi H. Gass, Ian Harvey, Andrew D. Newman, Karen Wilson ORCID, Adam F. Lee
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Pd does it alone : Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols.