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Wiley-VCH Verlag, ChemInform, 24(37), 2006

DOI: 10.1002/chin.200624086

Elsevier, Tetrahedron: Asymmetry, 1(17), p. 151-160

DOI: 10.1016/j.tetasy.2005.11.022

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Parallel synthesis of modular chiral Schiff base ligands and evaluation in the titatium(IV) catalyzed asymmetric trimethylsilylcyanation of aldehydes

Journal article published in 2006 by Belén Rodríguez, Mireia Pastó, Ciril Jimeno, Miquel A. Pericàs ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Highly modular tridentate Schiff base ligands arising from enantiopure epoxyalcohols have been prepared and evaluated in catalysis using parallel methods. The key structural motifs and experimental parameters have been identified, allowing enantioselectivities of up to 77% ee in the titatium-catalyzed trimethylsilyl cyanide addition to aldehydes.