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Sociedade Brasileira de Ciência do Solo, Revista Brasileira de Ciência do Solo, 5(38), p. 1506-1514, 2014

DOI: 10.1590/s0100-06832014000500016

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Animal manure phosphorus characterization by sequential chemical fractionation, release kinetics and 31P-NMR analysis

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Phosphate release kinetics from manures are of global interest because sustainable plant nutrition with phosphate will be a major concern in the future. Although information on the bioavailability and chemical composition of P present in manure used as fertilizer are important to understand its dynamics in the soil, such studies are still scarce. Therefore, P extraction was evaluated in this study by sequential chemical fractionation, desorption with anion-cation exchange resin and 31P nuclear magnetic resonance (31P-NMR) spectroscopy to assess the P forms in three different dry manure types (i.e. poultry, cattle and swine manure). All three methods showed that the P forms in poultry, cattle and swine dry manures are mostly inorganic and highly bioavailable. The estimated P pools showed that organic and recalcitrant P forms were negligible and highly dependent on the Ca:P ratio in manures. The results obtained here showed that the extraction of P with these three different methods allows a better understanding and complete characterization of the P pools present in the manures.