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Published in

American Institute of Physics, The Journal of Chemical Physics, 18(124), p. 184307

DOI: 10.1063/1.2194551

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A molecular-beam optical Stark study of lines in the (1,0) band of the FΔ7∕24-XΔ7∕24 transition of iron monohydride, FeH

Journal article published in 2006 by Timothy C. Steimle, Jinhai Chen, Jeremy J. Harrison ORCID, John M. Brown
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Data provided by SHERPA/RoMEO

Abstract

A supersonic molecular beam of iron monohydride, FeH, has been generated using a laser ablation/chemical reaction scheme and probed at near-natural linewidth resolution by optical Stark spectroscopy utilizing laser-induced fluorescence detection. The observed Stark splitting in Q(3.5) and R(3.5) lines of the F4delta(7/2) <-- X4delta(7/2) (1,0) transition were analyzed to determine values for the magnitudes of the permanent electric dipole moments, absolute value(mu), which were found to be 2.63(3) and 1.29(3) D for the X4delta (v = 0) and F4delta (v = 1) states, respectively. A comparison with ab initio theoretical predictions is made. The lambda doubling in the low-J levels of the F4delta(7/2) (v = 1) state is also modeled.