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Wiley, Angewandte Chemie International Edition, 30(52), p. 7772-7775, 2013

DOI: 10.1002/anie.201303245

Wiley, Angewandte Chemie, 30(125), p. 7926-7929, 2013

DOI: 10.1002/ange.201303245

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Shaping Micelles: The Interplay Between Hydrogen Bonds and Dispersive Interactions

Journal article published in 2013 by Iker León ORCID, Judith Millán ORCID, Emilio J. Cocinero ORCID, Alberto Lesarri ORCID, José A. Fernández ORCID
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This paper is available in a repository.

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Abstract

A subtle interplay: In the formation of a 1.6 nm micelle containing up to six molecules of propofol, a hydrogen-bond network is shown to influence the structure of the micelle, whereas the nonpolar groups arrange in such a way that the remaining noncovalent interactions are maximized. Such globular structures present a characteristic signature in the IR spectrum that will allow their identification in more complex media.