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Wiley, European Journal of Organic Chemistry, 4(2014), p. 719-724, 2013

DOI: 10.1002/ejoc.201301379

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Chiral Optical Properties of Phenyloxazoline Derivatives that Appear Only in the Solid State: Solid State Chiral Optical Properties of Phenyloxazoline Derivatives

Journal article published in 2013 by Masato Hirayama, Yuhei Kobayashi, Yuki Tanaka, Tomohiro Sato, Takunori Harada, Nobuo Tajima, Reiko Kuroda, Michiya Fujiki ORCID, Yoshitane Imai
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Unlike in the solution state, the circularly polarized luminescence (CPL) of the chiral oxazoline compound 4-(4-isopropyl-4,5-dihydrooxazol-2-yl)benzonitrile, having one oxazoline unit, was observed in the solid state. On the other hand, although the CPL of the chiral oxazoline compound 1,4-bis(4-isopropyl-4,5-dihydrooxazol-2-yl)benzene, having two oxazoline units, was not observed, its circular dichroism (CD) property changed significantly according to the state (i.e., solution or solid state).