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American Chemical Society, Inorganic Chemistry, 16(48), p. 7519-7521, 2009

DOI: 10.1021/ic901073w

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A Large-Surface-Area Boracite-Network-Topology Porous MOF Constructed from a Conjugated Ligand Exhibiting a High Hydrogen Uptake Capacity

Journal article published in 2009 by Xi-Sen Wang, Shengqian Ma ORCID, Shengqian, Daqiang Yuan, Ji Woong Yoon, Young Kyu Hwang, Jong-San Chang, Xiaoping Wang, Mads Ry Jørgensen, Yu-Sheng Chen, Hong-Cai Zhou
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A new porous metal-organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m(2)/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.